The first guy (named Yu Guangbiao) who hit Duan Yu happened to make contact with the Shan Zhong acupoint on Duan Yu's body, the only place that had the ability to absorb energy at that particular point in time. Details below.
Quote wuxiapedia.com: Initial effects of learning the Mystical Skill of Northern Darkness
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When Yu Guangbiao struck Duan Yu on the Shan Zhong acupoint, Yu's arm went numb and limp at once. In addition, Yu felt a brief moment of emptiness in his chest. As for Duan, he did not feel anything on the spot that he had been hit, although the punch had produced a rather loud sound. This was because the energy in Yu's punch had been absorbed into the 'sea' of energy in Duan's Shan Zhong acupoint and stored there. The Shan Zhong acupoint was also the place where the 'True Energy of Northern Darkness' (Bei3 Ming2 Zhen1 Qi4 北冥真气) was accummulated. Despite having practised the Mystical Skill of Northern Darkness a few times, Duan could still be considered a man without any foundations in internal strength. Therefore, he had absolutely no ability to take in another person's internal strength through the Shao Shang acupoint on his thumb, and send it along the Hand Taiyin Channel of the Lung and the Ren Channel for final storage in the Shan Zhong acupoint. But when Yu struck Duan's Shan Zhong acupoint and sent some internal strength into it, Duan could not resist the flow of energy into his body at all. Duan felt nauseous after Yu's internal strength gathered in his Shan Zhong acupoint; when he thought about the Ren Channel and the Hand Taiyin Channel of the Lung, he could feel a faint stream of warmth flowing through the two channels before returning to the Shan Zhong acupoint. The nausea disappeared after that, an indication that Yu's internal strength had taken up permanent residence in Duan's body (Chapter 5).